Everything about Concentrations totally explained
In
chemistry,
concentration is the measure of how much of a given
substance there's mixed with another substance. This can apply to any sort of chemical mixture, but most frequently the concept is limited to
homogeneous solutions, where it refers to the amount of
solute in a substance.
To
concentrate a solution, one must add more solute, or reduce the amount of solvent (for instance, by selective
evaporation). By contrast, to
dilute a solution, one must add more solvent, or reduce the amount of solute.
Unless two substances are
fully miscible there exists a concentration at which no further solute will dissolve in a solution. At this point, the solution is said to be
saturated. If additional solute is added to a saturated solution, it won't dissolve (except in certain circumstances, when
supersaturation may occur). Instead,
phase separation will occur, leading to either coexisting phases or a
suspension. The point of saturation depends on many variables such as ambient temperature and the precise chemical nature of the solvent and solute.
Analytical concentration includes all the forms of that substance in the solution.
Qualitative description
Often in informal, non-technical language, concentration is described in a
qualitative way, through the use of adjectives such as "dilute" or "weak" for solutions of relatively low concentration and of others like "concentrated" or "strong" for solutions of relatively high concentration. Those terms relate the amount of a substance in a mixture to the observable intensity of effects or properties caused by that substance. For example, a practical rule is that the more concentrated a
chromatic solution is, the more intensely colored it is.
Quantitative notation
For scientific or technical applications, a qualitative account of concentration is almost never sufficient; therefore
quantitative measures are needed to describe concentration. There are a number of different ways to quantitatively express concentration; the most common are listed below.
They are based on
mass,
volume, or
both. Depending on what they're based on it isn't always trivial to convert one measure to the other, because knowledge of the density might be needed to do so. At times this information may not be available, particularly if the temperature varies.
Mass versus volume
Some units of concentration — particularly the most popular one, molarity — require knowledge of a substance's volume, which unlike mass is variable depending on ambient temperature and pressure. In fact
(partial) molar volume can even be a function of concentration itself. This is why volumes are not necessarily completely additive when two liquids are added and mixed. Volume-based measures for concentration are therefore not to be recommended for non-dilute solutions or problems where relatively
large differences in temperature are encountered (for example for
phase diagrams).
Unless otherwise stated, all the following measurements of volume are assumed to be at a standard state temperature and pressure (for example 25 degrees Celsius at 1 atmosphere or 101.325 kPa
). The measurement of mass doesn't require such restrictions.
Mass can be determined at a precision of < 0.2 mg on a routine basis with an analytical
balance and more precise instruments exist. Both solids and liquids are easily quantified by weighing.
The volume of a liquid is usually determined by calibrated glassware such as burettes and volumetric flasks. For very small volumes precision syringes are available. The use of graduated beakers and cylinders isn't recommended as their indication of volume is mostly for decorative rather than quantitative purposes. The volume of solids, particularly of powders, is often difficult to measure, which is why mass is the more usual measure. For gases the opposite is true: the volume of a gas can be measured in a gas burette, if care is taken to control the pressure, but the mass isn't easy to measure due to buoyancy effects.
Molarity
» See also:
Molar solution Molar concentration
Molarity (mol/L, molar, or M) or
molar concentration denotes the number of
moles of a given substance per
liter of solution. M = mol/L. For instance:
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